Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2 N,P}methylpalladium(II) dichloromethane hemisolvate
نویسندگان
چکیده
In the title compound, [Pd(CH(3))Cl(C(25)H(22)NPS)]·0.5C(2)H(2)Cl(2), the Pd(II) atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thio-phene ring is equally disordered over two orientations and the dichloro-methane solvent mol-ecule is disordered about an inversion centre.
منابع مشابه
Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]-2,6-diisopropylaniline-κ2 P,N}platinum(II)
The title compound, [PtCl(2)(C(31)H(32)NP)], is a Pt(II) complex with an NPCl(2) coordination sphere in which the Pt(II) atom is coordinated to the imino N and phosphane P atoms of the ligand and to two cis Cl ions, giving a slightly distorted square-planar geometry. The P-Pt-N angle is 89.80 (5)° and the corresponding angle between the Cl ions is 87.92 (2)°.
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